(1,2-Bis((R,R)-2,5-diethyl-1-phospholidinyl)benzene)(1,5-cyclooctadiene)rhodium(1+) trifluoromethanesulfonate

CAS Registry Number®

136705-77-6

CAS Name

(1,2-Bis((R,R)-2,5-diethyl-1-phospholidinyl)benzene)(1,5-cyclooctadiene)rhodium(1+) trifluoromethanesulfonate

Molecular Formula

C30H48P2Rh.CF3O3S

Cite this Page

(1,2-Bis((R,R)-2,5-diethyl-1-phospholidinyl)benzene)(1,5-cyclooctadiene)rhodium(1+) trifluoromethanesulfonate.   CAS Common Chemistry.   CAS, a division of the American Chemical Society, n.d.   http://commonchemistry.cas.org/detail?cas_rn=136705-77-6 (retrieved 2024-11-13) (CAS RN: 136705-77-6).  Licensed under the Attribution-Noncommercial 4.0 International License (CC BY-NC 4.0).

Other Names and Identifiers

InChI

InChI=1S/C22H36P2.C8H12.CHF3O3S.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/q;;;+1/p-1/t17-,18-,19-,20-;;;/m1.../s1

InChIKey

InChIKey=HZLILTNLWVOBFS-QFNVKMGQSA-M

SMILES

C(C)[C@H]1[P]2([Rh+]345([P]6(C=7C2=CC=CC7)[C@H](CC)CC[C@H]6CC)[CH]8=[CH]3CC[CH]4=[CH]5CC8)[C@H](CC)CC1.C(S(=O)(=O)[O-])(F)(F)F

Canonical SMILES

O=S(=O)([O-])C(F)(F)F.C=1C=CC2=C(C1)[P]3(C(CC)CCC3CC)[Rh+]456([CH]=7CC[CH]6=[CH]5CC[CH]74)[P]28C(CC)CCC8CC

Other Names for this Substance

  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-phenylene)bis[2,5-diethylphospholane-κP]]-, 1,1,1-trifluoromethanesulfonate (1:1)
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][1,1′-(1,2-phenylene)bis[2,5-diethylphospholane]-P,P′]-, [2R-[1(2′R*,5′R*),2α,5β]]-, salt with trifluoromethanesulfonic acid (1:1)
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][(2R,2′R,5R,5′R)-1,1′-(1,2-phenylene)bis[2,5-diethylphospholane-κP]]-, salt with trifluoromethanesulfonic acid (1:1)
  • Phospholane, rhodium(1+) deriv.
  • Rhodium(1+), [(1,2,5,6-η)-1,5-cyclooctadiene][1,1′-(1,2-phenylene)bis[2,5-diethylphospholane-κP]]-, [2R-[1(2′R*,5′R*),2α,5β]]-, salt with trifluoromethanesulfonic acid (1:1)

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